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Fabric softener is a scam
(lemm.ee)
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Don't be mean. I promise to do my best to judge that fairly.
This is pure conjecture, but my guess is that the film of fabric softener left on the clothes would interfere with the fire retardant fibers/may be flammable itself.
From my understanding, the old fire gear I wore as a much younger man, the fabric was treated with special chemicals that could be washed out if not laundered correctly.