A very common mistake is to commute what you'd drive. In many cases you'd do better on paths and neighborhood streets. For example, maybe part of an unavoidable highway segment has a frontage road. Hop off onto the frontage for that segment, even if it's technically 60 seconds slower.
Google Maps is a decent start, though imperfect in detail (routing through a busy park on footpaths, or not routing through a park that has a good dirt path). Use street view and OpenStreetMaps to explore ways that auto routing won't pick.
+1 to the suggestions on starting with shorter trips. They'll work out any kinks in your setup and give you time to become confident on your bike.