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Unexpected use of FR2 of the week: Phenolic gears
(aussie.zone)
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There are some youtube videos of people machining them (sadly my browser does not support smell). Looks like you treat it like any other solid material: hobb or mill the teeth. This is much more expensive than 3d printing.
You might be surprised by your 3d printed gears. If you keep the detail size large they work really well, but backlash is definitely an issue.