You are confusing yourself with hardware and different standards. SATA 3 can max out at 6Gb/s. Generic HDD works around 220mb/s, 1G network is 110mb/s, 2.5G network is around 300mb/s.
So to give you a perspective, if you have 1G as a local network, you can't max out a HDD capability, with 2.5G you double the performance, saturating the HDD, if you want more you need a generic 2.5" SSD, if you want to saturate the SSD you need 10G, in that case M2 SSD start to make sense.
Remember that if you want to go 2.5G, you need all the infrastructure of your home to work around that speed, not only the Nas.