I'm not exactly sure how Backup Calling works (I don't think my phone has that feature) but would "Ask each time" be a sufficient option for you? That's how I usually set things up when I'm traveling and have a travel eSIM.
Ask each time lets me pick the SIM used for the call. I always use the second SIM, the first one doesn't support calls. What I want is routing calls with the cellular data of the first SIM. On my phone backup calling is tied to SIM switch, when one is on so is the other. SIM switch is automatically swapping cellular data to a SIM if it receives a call (which I can't, the calls SIM has no data)
Android
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