Putting it in park at highway speeds depends mostly on how new the car is. Newer cars will put the transmission in neutral and probably yell at you with the dash. Older cars the parking lock isn't strong enough to lock up the wheels at speed, so it'll grind and clatter or just break. Ruining the parking lock.
Turning the car off on the highway just makes you coast to a stop. Depending on if its an automatic or manual transmission; you might loose power assist on the steering if the engine stops spinning. Pulling the key out normally activates the steering wheel lock. Which is a whole other problem if you are still moving... Some automatics prevent you from removing the key if the transmission isn't in park though...