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Step 1: Be incompetent.
So you see no difference in lethal injection and filling a room with nitrogen? If not, there's no point discussing it with you. But I'll give you a hint! Worst case, there's not enough NO2 to cause death, so the subject gets stoned as balls and they introduce more.
This ain't rocket science.
I see no difference in an incompetent person trying something they are not qualified to do and then trying to do another thing they are unqualified to do. I expect them to fail at both.
You also don't appear to understand how the NO2 process works. It isn't that they just need to add more N02, they also need to remove the oxygen AND CO2 at the same time. That is actually fairly complicated and requires knowledge on air movement in a restricted space. If they can't properly dose someone with needles, good luck on them doing it right with airflow.
This isn't a "gas chamber" type of execution. They're putting a mask on the person with nitrogen gas. Though the state's executioners are so incompetent that they'll probably end up gassing themselves.