Okay so I’ve done some digging and got my VM to boot up! This is not Podman’s fault, I got lazy setting up Proxmox and never really learned LVM volume storage, while internally on the VM it shows 90Gb used of 325Gb Proxmox is claiming 377Gb is used on the LVM-Thin partition.
I’m backing up my files as we speak, thinking of purging it all and starting over.
Edit: before I do the sacrificial purge This seems promising.