If you have pieces of metal that you can filter out. Metals in water are usually in ionic form, they are "chelated" by water in solutions. Unless some salt is created and precipitate, solved metals distribuite over the solution to avoid concentration gradients.
So the answer is: what metal are you talking about? What is its form and concentration? Most likely, if you couldn't see depositions before boiling it, metal ions will likely stay in solution.
Boiling water is used to kill biological organisms. If you want to get "pure" water you need to distillate it or filter it with materials that can capture ions
You don’t have to wait for it to cool. As water evaporates the dissolved solids in it reach a higher concentration. If the concentration becomes greater than the molecule’s solubility it will precipitate and fall to the bottom.
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