It is because radicalization is more than a cognitive process. It is as much social and psychological. Intelligence alone is a pretty bad predictor of a lot of things we like to think only depend on intelligence. While there is some causation, it is not a vacuum or often even the biggest predictor of many things.
Radicalization is the thing that makes you believe in things that can't be real. Making people believe a lot of things is surprisingly easy. Look into religions. While I don't believe and you might not, a lot of intelligent people throughout world history have. There might be a correlation between intelligence and atheism these days, but the effect is far from linear.