No, the way humans know things and LLMs know things is entirely different.
The flaw in your understanding is believing that LLMs have internal representations of memes and cats and cars. They do not. They have no memories or internal facts... whereas I think most people agree that humans can actually know things and have internal memories and truths.
It is fundamentally different from asking you to forget that cats exist. You are incapable of altering your memories because that is how brains work. LLMs are incapable of removing information because the information is used to build the model with which they choose their words, which is then undifferentiatable when it's inside the model.
An LLM has no understanding of anything you ask it and is simply a mathematical model of word weights. Unless you truly believe humans have no internal reality and no memories and simply say things based on what is the most likely response, you also believe humans and LLM knowledge is entirely different to each other.