I'm not familiar with Pikapods but Monica v4 has trouble with notifications. First you need to ensure it's been configured right to even send a test email, this can be triggered with a command if you have access:
php artisan monica:test-email
Various Monica environment variables must be set to configure this, it should be in the docs somewhere if not I can fish my config out for you.
Even once that's working you'll need Monica to run its regular jobs for sending notifications, there's config for that too. Finally the code has bugs and will often miss reminders in my experience. There are some open bugs still on this and I guess the devs have moved onto their rewritten version (chandler):