"There is not a native app on Steam deck today," said Andrew Fear, GFN boss, back in January. "Use a Chromium browser to make it work. I would say that both Nvidia and Valve, I think we're both interested in making [GeForce Now on Steam Deck] better. But we don't have any announcements on a native app coming to Steam."
Steam allows you to stream from another computer you have, GeForce Now is cloud based and depending on the subscription it can have a 4080 equivalent gpu.