Corrosives have limits, they can’t just keep dissolving stuff forever.
Thus, the explosive assist for initial penetration. The type would depend on the composition of the concrete, you'd probably be more successful targeting the tension strength of the fibers or metals instead of the compression strength of the cement.
And what would “total failure” look like? It’s a mountain, it’s not going to just collapse into goo.
You don't need goo, you just need enough weakening that it no longer supports the 250' of loose rubble atop it and collapses into the interior space.