He was, but it's not self-defense if the only reason you are in that situation is because you created it.
If I put myself and another person in some room that's rigged to lock and not unlock until the other person is dead.. Technically I am fighting for my life, but it's not self-defense because this wouldn't have happened if I didn't seek this out intentionally...
And that's basically what Rittenhouse did waving that gun around