That doesn't make any sense, sure it will reflect slightly more heat from your body back inside but that is negligible because the vast majority of body cooling happens due to convection and/or evaporative cooling and/or "contact cooling" depending on heat/humidity/how loose your clothes are. Radiation plays very little effect in that cooling.
Basically consider this: your body is emitting black-body radiation at 310K, and the sun is emitting black-body radiation at 6000K (+ a bunch of other radiation coming from all the fusion happening inside). Which one is a more important factor when you're deciding the reflectivity of the shield between yourself and the rest of the universe?